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1 In order to obtain the limiting molar conductivities of H and A , the molar conductivities (K) are measured for the tetraalkylammonium salt of A (R4NA) and a strong acid (eg CF3SO3H), and their limiting molar conductivities KI are obtained by calculation Using the known kI values of R4N+ and CF3SO , 3 the kI values of H+ and A are obtained 2 The molar conductivity of HA is measured as a function of its concentration, ca, and the data are analyzed appropriately, according to the mechanism of the acid dissociation: (i) If HA is a strong acid and is completely dissociated (HA H++A ), the K c1/2 relation should have the Onsager slope at low concentration regions From a this, we can confirm the complete dissociation of HA and get the value of KI (HA).

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The example bit rates for di erent parameter combinations without overhead considerations for di erent transport format and resource combinations (TFRCs) is shown in Table 4.4. The BTS scheduler can allocate the data rates for a single user to obtain a continuous high bit rate connection or to multiple users when the average user data rate is divided between the number of users sharing the resources. Obviously, at cell edge the data rates are more restricted than locations close to the base station site. It is also important to understand that these data rates are not typically end-to-end data rates. The core network may ask for, say, a 1-Mbps peak rate which then momentarily over a 2-ms TTI may be, say, 3.6 Mbps. This is hidden from the core network by resulting data rate averaging when sharing HS-DSCH resources among several users (as was discussed in 3). When we take into account RLC/MAC headers and x the PDU size to be 320 bits, then we get the RLC layer data rates for di erent terminal categories (see Table 4.5). For the application level the di erence is then less than 5% due to the Internet Protocol (IP) header overhead.

If more accurate values of KI (HA) are needed, the data are analyzed by one of the theories covered in Section 711 (ii) If HA is a weak acid but dissociates simply by HA 3 H++A , the relation 2 Ka = K=KI 2 ca holds approximately If the value of K=KI 2 ca is independent of ca, we can consider that the dissociation reaction is simple and Ka is equal to that value (iii) If HA is a weak acid and the dissociation is accompanied by a homoconjugation reaction: 3 HA 2 H A ; A HA 3 HA 2 2 we determine the dissociation constant, Ka, and the homoconjugation constant, K f HA , using the French-Roe equation [41], which holds when only a small 2 fraction of HA is dissociated into A and HA .

Source: Data derived from [93].

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2 ( 1=2 1=2 1 Ka I K ca ca f K HA ca KI 2HA fKa K f HA g1=2 2 K HA K f HA 2 2 7:17 Here, KI (2HA) is the sum of kI for H+ and HA If we plot the relation be2 tween Kfca ca 1=K f HA g1=2 and ca, varying the value of Kf(HA ), a straight 2 2 line is obtained for the most suitable Kf(HA )-value Then the slope and the inter2 cept of the line are equal to KI 2HA fKa K f HA g1=2 and KI HA 2 fKa =K f HA g1=2 , respectively If HA is not weak enough, Eq (717) should be 2 modified [40] (iv) If HA is a weak acid and its molar conductivity K is independent of concentration ca, there is a dissociation equilibrium as in Eq (7.

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