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changes during the oxidation-reduction processes can be quantitatively measured as frequency-potential curves, simultaneously with the current-potential curves. The cyclic voltammogram in Fig. 9.9(a) shows that the oxidation of polyaniline in 0.5 M LiClO4-AN proceeds in two steps. The frequency-potential curve, on the other hand, shows that, in both steps, the doping of ClO occurs. 4 3) Application of conducting polymers: Doped conducting polymers behave like metals, while undoped conducting polymers behave like insulators or semiconductors. The reversible conversion between the metallic and the insulating (or semiconducting) states can be realized simply by switching the potential of the conducting polymer. Conducting polymers have a wide applicability, as listed in Table 12.1. They include applications as insulating (or semiconducting) material, applications as metallic material, applications of reversible conversions between insulating metallic states, and applications of the specific functions of the dopant counter ions. The use of conducting polymers as electrodes in lithium secondary batteries and supercapacitors (pseudocapacitors) was discussed above. From the standpoint of electrochemistry in non-aqueous solutions, the use as electrochromic materials is also interesting. Conducting polymers usually have different colors between the doped- and undoped-states. The color change of the transmitted light by the undoped doped conversion is red blue for the polythiophene film, yellow blue for the polypyrrole film, and light yellow green for polyaniline. In principle, the color switching is possible by use of a cell composed of an optically transparent indium-tin oxide (ITO) glass electrode coated with a conducting polymer film 7), a bare ITO glass electrode, and an electrolyte solution, as shown in Fig. 12.4, and by applying a pulse voltage between the two electrodes to switch the conducting polymer between doped- and undoped-states. For the recent status of the applications of conductive polymers to electrochromic displays, mirrors, and windows, see Ref. [11].

where v is the vector velocity of the body in the rotating coordinate frame, O is the inertial rotation rate vector of the coordinate frame (i.e., with direction parallel to the rotation axis and magnitude equal to the rotation rate), and aCoriolis is the apparent acceleration acting on the body in the rotating coordinate frame. Rotating Coriolis Effect Gyroscopes The gyroscopic effect in momentum wheel gyroscopes can be explained in terms of the Coriolis effect, but there are also gyroscopes that measure the Coriolis acceleration on the rotating wheel. An example of such a two-axis gyroscope is illustrated in Fig. 6.3. For sensing rotation, it uses an accelerometer mounted off-axis on the rotating member, with its acceleration input axis parallel to the rotation axis of the base. When the entire assembly is rotated about any axis normal to its own rotation axis, the accelerometer mounted on the rotating base senses a sinusoidal Coriolis acceleration. The position and velocity of the rotated accelerometer with respect to inertial coordinates will be P T U x t rT sin Odrive t U; R S 0 v t d x t dt 6:11 P sin Odrive t 0 where Odrive is the drive rotation rate and r is the offset distance of the accelerometer from the base rotation axis. Q 6:12 cos Odrive t Q 6:10

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The ability to use monetary and fiscal policy to stimulate the economy is important because you always want to end a recession and return the economy to producing at the full-employment output level as quickly as possible. As we explain in 6, the full-employment output level symbolised by Y* is the amount of output the economy produces at full employment, which occurs when every person who wants a full-time job can get one. If the economy goes into recession and produces less than Y* worth of output, millions of people lose their jobs because firms need fewer workers to produce the smaller amount of output. Worse yet, the unemployment rate remains high until output returns to the full-employment level. Monetary and fiscal policy are useful precisely because they can help return the economy to producing at Y* as soon as possible; they can shorten the period of frustration and misery that the unemployed endure. Take a look at Figure 7-1, which shows how monetary and fiscal policy can be used to stimulate aggregate demand and return an economy to producing at Y* as quickly as possible after the economy is hit with a negative demand shock. (As we explain in 6, negative demand shocks are things that unexpectedly decrease aggregate demand, such as a drop in consumer confidence.)

Relationship between the standard rate constant (log ks) for the reaction / Na+ + e Na(Hg) and the solvation energies of the Na+ ion [23 a].

The European roaming capability, subsequently extended to international roaming, was followed by the EREG (subsequently IREG) group for the technical aspects and BARG for tariffs/billing and accounting. The contributions given by TADIG and by SERG have been already presented in 3, Sections 2 and 3. In terms of charging principles the main decisions related to mobile terminated calls. Speci cally it was decided that a mobile client will not be charged for air time either when he/she is in his/her home country and when he/she is roaming in another country. In the last case the mobile client will have to pay for the international extension from his country to the visited one. Long discussions took place in relation to optimized routing, that is a routing which reduces to the minimum the connection length and optimizes the quality. EREG proposed technical solutions already in 1989, but the commercial position expressed by BARG was contrary to an extensive use of such technique. Finally, accepting the proposal from BARG, the MoU plenary decided not to introduce optimized routing for international calls. Years later the optimized routing for calls originated in the same Country where the mobile client is a visiting roamers was recommended, but, as far as I know, it is not yet practically used. Commercial issues against optimized routing have been:

Make relevant domain architectures Drafting project-start architecture Support projects Consolidate project results

Exercising the class nth imm of year functionality in an interactive Python session goes like this:

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